Reducing Iron Oxides without Carbon by using Hydrogen-Plasma

HORIZON.1.1HORIZON-ERCID: 101054368
EC Contribution
€24,918
Consortium Size
1 orgs
Summary

With 1.8 billion tons produced per year, steel is the dominant metallic material. It can be recycled by melting scrap, a resource satisfying at most 30% of the demand. Hence, fresh steel must be produced in huge amounts, from oxide minerals reduced by CO in blast furnaces, followed by partial removal of C by O2 in converters. These two processes create ~2.1 tons CO2 per ton of steel, qualifying steelmaking as the largest single greenhouse gas emitter on earth (~8% of all emissions). ROC tackles the fundamental science needed to drastically cut these staggering CO2 numbers, by up to 80% and beyond. This is the biggest single leverage we have to fight global warming. The disruptive approach of ROC lies in (1) using H instead of C as reductant and (2) merging the multiple steps explained above into a single melting plus reduction process which can run with green electricity, namely, an electric arc furnace operated with a H-containing reducing plasma. ROC’s approach is feasible as it can be upscaled by modifying existing furnace technology. The motivation is that solid Fe from other synthesis methods such as direct reduction must anyway be melted after reduction. Project ROC also addresses hybrid processes, where partially reduced oxides from direct reduction are fed into a reducing plasma, for high energy and H2 efficiency at fast kinetics and high metallization. Project ROC explores the physical and chemical foundations of these processes, down to atomistic scales, with a blend of instrumented laboratory furnaces, characterization, simulation and machine learning. Specific topics are the elementary nucleation, transport and transformation mechanisms, mixed scrap and ore charging, influence of contaminants from feedstock, plasma parameters, C-free electrodes, slag metallurgy and the role of nanostructure. Drastic reduction of CO2 is the biggest challenge of our time and project ROC explores how steelmaking can contribute to it by cutting its emissions by 80% and more.

Consortium (1)

Project Results (11)

Source: CORDIS, the EU research results database.

Publications (10)
Green Ironmaking at Higher H2 Pressure: Reduction Kinetics and Microstructure Formation During Hydrogen-Based Direct Reduction of Hematite Pellets
Journal of Sustainable Metallurgy· 2024DOI
Özge Özgün; Imants Dirba; Oliver Gutfleisch; Yan Ma; Dierk Raabe
Green steel from red mud through climate-neutral hydrogen plasma reduction
Nature 625(7996), 703-709 (2024). doi:10.1038/s41586-023-06901-z· 2024DOI
Jovičević-Klug, Matic; Souza Filho, Isnaldi R.; Springer, Hauke Joachim; Adam, Christian; Raabe, Dierk
Mechanisms and elemental partitioning during simultaneous dephosphorization and reduction of Fe-O-P melts by hydrogen plasma
Acta Materialia· 2024DOI
Ömer K. Büyükuslu, Leonardo S. Aota, Dierk Raabe, Hauke Springer, Isnaldi R. Souza Filho
Sustainable Ironmaking Toward a Future Circular Steel Economy: Exploiting a Critical Oxygen Concentration for Metallurgical Cu Removal from Scrap‐Based Melts
steel research international· 2024DOI
Isnaldi R. Souza Filho, Alisson K. da Silva, Ömer K. Büyükuslu, Dierk Raabe, Hauke Springer
The Optical Spectra of Hydrogen Plasma Smelting Reduction of Iron Ore: Application and Requirements
steel research international· 2024DOI
Henri Pauna; Daniel Ernst; Michael Zarl; Isnaldi Rodrigues de Souza Filho; Michael Kulse; Ömer Büyükuslu; Matic Jovičević‐Klug; Hauke Springer; Marko Huttula; Johannes Schenk; Timo Fabritius; Dierk Raabe
Effect of Pore Formation on Redox-Driven Phase Transformation
Physical Review Letters· 2023DOI
Xuyang Zhou; Yang Bai; Ayman A. El-Zoka; Se-Ho Kim; Yan Ma; Christian H. Liebscher; Baptiste Gault; Jaber R. Mianroodi; Gerhard Dehm; Dierk Raabe
Fundamentals of Green Steel Production: On the Role of Gas Pressure During Hydrogen Reduction of Iron Ores
JOM-Journal of the Minerals Metals & Materials Society· 2023DOI
I. R. Souza Filho; Y. Ma; D. Raabe; H. Springer
Green steel at its crossroads: Hybrid hydrogen-based reduction of iron ores
Journal of Cleaner Production· 2023DOI
Isnaldi R. Souza Filho, Hauke Springer, Yan Ma, Ankita Mahajan, Cauê C. da Silva, Michael Kulse, Dierk Raabe
How much hydrogen is in green steel?
npj Materials Degradation· 2023DOI
Özge Özgün; Xu Lu; Yan Ma; Dierk Raabe
Reducing Iron Oxide with Ammonia: A Sustainable Path to Green Steel
Advanced Science· 2023DOI
Yan Ma; Jae Wung Bae; Se‐Ho Kim; Matic Jovičević‐Klug; Kejiang Li; Dirk Vogel; Dirk Ponge; Michael Rohwerder; Baptiste Gault; Dierk Raabe
Other Results (1)
Periodic Reporting for period 1 - ROC (Reducing Iron Oxides without Carbon by using Hydrogen-Plasma)