Biocarbon based Polymers for Sustainable Material Development

HORIZON.1.2HORIZON-TMA-MSCA-DN-JDID: 101073223
EC Contribution
€31,683
Consortium Size
16 orgs
Summary

D-Carbonize´s approach targets biocarbon recycling into valuable starting materials for the chemical/polymer industries and will primarily provide innovative low-carb catalysis solutions. The use of biocarbon is advantageous in many respects as it is renewable, generally abundant and non-toxic, and it represents easy-to-handle carbon reagents even on larger scale. Despite the lack of universal (catalytic) strategies available for biocarbon valorization into monomers and polymers, recent advances in catalysis science have demonstrated the engineering and use of new promising metal- and organo-catalysts with high potential to overcome these limitations, thereby creating the necessary feasibility to transform biocarbon into (1) fine chemicals such as carbonates, carbamates, carboxylic acids, and esters, (2) pharmaceutical synthons, and (3) biomass/CO2-based polymers. Thus, catalysis has already been shown to be a useful technology for biocarbon valorization but has been rarely used in the wider context of new and functional biocarbon based monomer/polymer development. The use of the latter helps to shape the future of functionalized poly-esters/carbonates/amides and their subsequent utilization in novel tailor-made and commercially relevant materials. Furthermore, this project will also explore depolymerization pathways to recycle the synthesized polymers obtaining new monomers and/or other added-value molecules that could re-enter the loop and be used in new polymers and materials. The network will recruit 12 doctoral candidates, who will be awarded double doctoral degrees by two universities in two different countries at the end of the training program. D-Carbonize brings together leading high-education institutions, research centers and companies to form an innovation community able to offer excellent research and training both in R&D and entrepreneurship.

Consortium (16)

Project Results (8)

Source: CORDIS, the EU research results database.

Publications (4)
Domino Synthesis of Functionalized Cyclic Acetals From Organic Carbonates
Advanced Synthesis & Catalysis· 2025DOI
Natalia Kulbacka, Wangyu Shi, Sophie M. Guillaume, Jean‐François Carpentier, Jordi Benet‐Buchholz, Arjan W. Kleij
Enabling a Diversity‐Oriented Catalytic Atom Looping of a Biobased Polycarbonate
ChemSusChem· 2025DOI
Enrico Lanaro, Thirusangumurugan Senthamarai, Stephen K. Hashmi, Arjan W. Kleij
Palladium-catalyzed methoxycarbonylation of a commodity CO2-sourced δ-valerolactone
Molecular Catalysis· 2025DOI
Hussein Tabaja, Bruno Grignard, Christophe Detrembleur, Matthias Beller, Sophie M. Guillaume, Jean-François Carpentier
Synthesis and depolymerization studies of biohybrid polycarbonates derived from terpenes
Polymer Chemistry· 2025DOI
Thirusangumurugan Senthamarai; Enrico Lanaro; Jack Tinker; Antoine Buchard; Arjan W. Kleij
Deliverables (3)
Other Results (1)
Periodic Reporting for period 1 - D-Carbonize (Biocarbon based Polymers for Sustainable Material Development)