Piezoelectricity in 2D-materials: materials, modeling, and applications

HORIZON.1.2HORIZON-TMA-MSCA-SEID: 101131229
EC Contribution
€4,830
Consortium Size
8 orgs
Summary

Piezoelectricity in two-dimensional (2D) materials is increasingly important because of its potential in realizing thin yet efficient and flexible piezoelectric devices. In contrast to traditional three-dimensional (3D) piezo- and ferroelectrics that are prone to size effects, piezoelectricity in 2D materials may be controlled by flexoelectricity and interfaces thus providing significant piezoelectric effect in ultrathin films and crystals. Equally important, the majority of 2D layered piezoelectrics found so far possess in-plane piezoelectricity and require bending of flexible substrates to activate piezoelectric effect. This severely limits their integration with modern Si technology. This project aims at strengthening the piezoelectric activity in 2D materials via interface and stress engineering and bond control in order to reach the maximum efficiency and other relevant figures of merit. The materials list includes hafnium-zirconium oxide (HZO), transition metal thio/selenophosphates (TPS), graphene on oxide substrates, and polymer PDVF. A comprehensive investigation of piezoelectricity in these 2D materials and their relevant device performance is still at an initial stage and needs European support. Concerning piezoelectric energy harvesting, Piezo2D will build a technology to provide local energy generation (microgenerators) from the nm- to the micro-scale to power nano- and microdevices. Piezo2D will do so by enhancing and deploying the combined powers of equilibrium and nonequilibrium thermodynamics and atomistic models with device physics and engineering. Research results will underpin future developments of nanoscale energy devices for decades to come. We will also develop new characterization techniques and metrology-inspired protocols aiming at future standards and their use in the industry. The multidisciplinary approach of Piezo2D brings together leading teams in theoretical physics, materials science, chemistry and instrumentation working in synergy

Consortium (8)

Project Results (16)

Source: CORDIS, the EU research results database.

Publications (13)
Electromechanical coupling in polaronic ceria
Journal of Physics: Energy· 2025DOI
Victor Buratto Tinti, Milica Vasiljevic, Mathias Grønborg, Huaiyu Chen, Valdemar Frederiksen, Innokenty Kantor, Jesper Wallentin, Henrik Bruus, Vincenzo Esposito
Ferro-ionic states and domains morphology in HfxZr1−xO2 nanoparticles
Journal of Applied Physics· 2025DOI
Eugene A. Eliseev, Sergei V. Kalinin, Anna N. Morozovska
Investigation of Ion Migration in CuInP2S6 Crystals by Raman Spectroscopy and Dielectric Spectroscopy
NATO Science for Peace and Security Series B: Physics and Biophysics, Nanotechnological Advances in Environmental, Cyber and CBRN Security· 2025DOI
D. Gál, A. Czitrovszky, L. Himics, M. Veres, T. Váczi, L. Péter, A. Molnar
Organic and Biological Piezoelectric Materials
Engineering Materials, Piezoelectric Polymers and Polymer Composites for Advanced Applications· 2025DOI
Hélder Baptista, Tomás Simões, Pavel Zelenovskii, Konstantin Romanyuk, Andrei Kholkin, Svitlana Kopyl
Resistive Switching and Charge Accumulation in Hf<sub>0.5</sub>Zr<sub>0.5</sub>O<sub>2</sub> Nanoparticles
The Journal of Physical Chemistry C· 2025DOI
Oleksandr S. Pylypchuk, Ihor V. Fesych, Victor V. Vainberg, Yuriy O. Zagorodniy, Victor I. Styopkin, Juliya M. Gudenko, Irina V. Kondakova, Lesya P. Yurchenko, Victor N. Pavlikov, Anna O. Diachenko, Mykhailo M. Koptiev, Mykhailo D. Volnianskii, Valentyn V. Laguta, Eugene A. Eliseev, Mikhail P. Trubitsyn, Anna N. Morozovska
Strain-Polarization Coupling in the Low-Dimensional Van der Waals Ferrielectrics
2024 IEEE 42nd International Conference on Electronics and Nanotechnology (ELNANO)· 2025DOI
Anna N. Morozovska, Hanna V. Shevliakova, Liubomyr M. Korolevych, Viktoriia Khist, Yulian M. Vysochanskii, Eugene A. Eliseev
The influence of electric field on the anisotropic dispersion of the flexocoupling induced phonons and ferrons in van der Waals ferrielectrics
Journal of Applied Physics· 2025DOI
Anna N. Morozovska, Eugene A. Eliseev, Yujie Zhu, Yulian M. Vysochanskii, Venkatraman Gopalan, Long-Qing Chen, Jia-Mian Hu
The role of flexoelectric coupling and chemical strains in the emergence of polar chiral nano-structures
Journal of Applied Physics· 2025DOI
Anna N. Morozovska, Salia Cherifi-Hertel, Eugene A. Eliseev, Victoria V. Khist, Riccardo Hertel, Dean R. Evans
Bending-induced isostructural transitions in ultrathin layers of van der Waals ferrielectrics
Acta Materialia· 2024DOI
Anna N. Morozovska, Eugene A. Eliseev, Yongtao Liu, Kyle P. Kelley, Ayana Ghosh, Ying Liu, Jinyuan Yao, Nicholas V. Morozovsky, Andrei L Kholkin, Yulian M. Vysochanskii, Sergei V. Kalinin
Quantitative 3-D Optical Birefringence in Peptide Bioelectrets
IEEE Transactions on Dielectrics and Electrical Insulation· 2024DOI
Charlie O’Mahony, Aladin Mani, Svitlana Kopyl, Daria Vasileva, Semen Vasilev, Vladimir Y. Shur, Andrei Kholkin, Christophe Silien, Syed A. M. Tofail
Size Effect of Negative Capacitance State and Subthreshold Swing in Van der Waals Ferrielectric Field‐Effect Transistors
Advanced Electronic Materials· 2024DOI
Anna N. Morozovska, Eugene A. Eliseev, Yulian M. Vysochanskii, Sergei V. Kalinin, Maksym V. Strikha
Tunable Ferroionic Properties in CeO<sub>2</sub>/BaTiO<sub>3</sub> Heterostructures
ACS Applied Materials & Interfaces· 2024DOI
Milica Vasiljevic, Francesco Chiabrera, Denis Alikin, Federico Motti, Achilles Bergne, Javier Zamudio-García, Xueping Qin, Deepak Dagur, Shinhee Yun, David Marrero-López, Giovanni Vinai, Ivano Castelli, Andrei Kholkin, Vincenzo Esposito
The strain-induced transitions of the piezoelectric, pyroelectric, and electrocaloric properties of the CuInP2S6 films
AIP Advances· 2023DOI
Anna N. Morozovska, Eugene A. Eliseev, Lesya P. Yurchenko, Valentyn V. Laguta, Yongtao Liu, Sergei V. Kalinin, Andrei L. Kholkin, Yulian M. Vysochanskii
Deliverables (2)
Other Results (1)
Periodic Reporting for period 1 - Piezo2D (Piezoelectricity in 2D-materials: materials, modeling, and applications)